In OF2, the Oxygen atom is the least electronegative one and hence it is placed in the centre. Fluorine is highly electronegative and has an electronegative value of 3.98, whereas Oxygen has an electronegative value of 3.44. The difference between the electronegativities of both these atoms is higher than 0.5, which makes the O-F bonds polar.1) The bonds in the polyatomic ion (CO3)^2-Â are classified as. A) ionic. B) metallic. C) nonpolar covalent. D) polar covalent. Â. 2) Which of the following phase changes has a positive value for its entropy change? A) boiling water. …We would like to show you a description here but the site won’t allow us. As a result of the difference in the electronegativities of B and Cl, the B–Cl bond is polar in nature. However, the BCl3 molecule is non-polar. This is because BCl3 is trigonal planar in shape. It is a symmetrical molecule. Hence, the respective dipole-moments of the B–Cl bond cancel each other, thereby causing a zero-dipole moment.CO 2 is a nonpolar substance. It occurs naturally in the Earth’s atmosphere as a trace gas. produced during respiration by all animals, fungi, and microorganisms that depend directly or indirectly on living or decaying plants for food. A colorless, odorless, incombustible gas resulting from the oxidation of carbon.CO3 2- (Carbonate) is Nonpolar. I'll tell you the polar or nonpolar list below. If you want to quickly find the word you want to search, use Ctrl + F, then type the word you want to search. List molecules polar and non polar. Molecules polar. 1-butanol.Question: Identify if the molecules are polar or nonpolar. Identify the bonds. A) CHF3 B) NO3-1 C) CO3-2 D) CF4 E) CH2O F) C2Br4 G) HCN The total valence electron is available for the Silicon tetrachloride (SiCl4) lewis structure is 32. The hybridization of the SiCl4 molecule is Sp 3. The bond angle of SiCl4 is 109.5º. SiCl4 is nonpolar in nature, although, its bonds are polar. The overall formal charge in Silicon tetrachloride is zero.In SO3 (below) you also have a trigonal planar structure, but in this case all the substituents are equal in electronegativity. (The electrons on the oxygen aren't pictured, but each has two pairs, just like above, sulfur has no electrons). So SO3 is nonpolar, and SO2 is polar because of substituent differences, but especially because of geometry.Expert Answer. CO3^2- ion is NON - POLAR because CO3^2- ion is trigonal planar geometry due to sp2 Hybridizat …. View the full answer. Here we are learning about CO32- lewis structure and characteristics. Carbonate (CO32-) is an anion which consists of two elements i.e. one carbon atom and three oxygen atoms. CO32- is an conjugate base of hydrogen carbonate. Most of the carbonic acid ions and salts have CO32- functional group in it. Alkali metal carbonates …Jun 27, 2020 · To determine if the bonds present in the CO32- ion are polar or non-polar, we look to the periodic table. Which is an ion with the formula of CO3 2? CO3 2– is carbonate.a carbonate is a salt ofcarbonic acid (H2CO3),characterized by the presence of thecarbonate ion, a polyatomic ion with the formula of CO3 2-.CO32– is an anion (a negative ... Is SO3 Polar Or Nonpolar. Because the valence electrons in sulfur trioxide (SO3) are shared equally in the molecular structure, it is a nonpolar molecule, and the Lewis structure of SO3 appears to be a well symmetrical structure. Its trigonal planar form, sulfur trioxide (SO3) is a nonpolar molecule. Each C–O bond in CO 2 is polar, yet experiments show that the CO 2 molecule has no dipole moment. Because the two C–O bond dipoles in CO 2 are equal in magnitude and …May 25, 2023 · For N-I bond; The electronegativity difference (ΔEN) = 3.16 – 2.66 = 0.5. This value lies between 0.4 to 1.7, which indicates that the bond between Nitrogen (N) and Iodine (I) is polar. Hence, each N-I bond is a polar covalent bond. But wait, we also have to look at the molecular geometry of NI3 to know whether it has a symmetric shape or not. 5 days ago · SF2 is a polar molecule but its bonding angle is very interesting. The bond angle of SF2 is 98 degree and that of H2O is 104 degrees. The reason for this fact is the presence of highly negative halogen fluorine. 2 fluorine atoms are present either side of the molecule. The presence of lone pair electrons causes negative-negative charge repulsion. 2 molecule is non-polar. The polar bonds in the bent H 2O molecule result in a net dipole moment, so H 2O is polar. In large organic molecules, such as drugs and vitamins, and in biomolecules, such as proteins, we often consider the number of polar groups within the molecule to determine the extent to which the overall molecule is polar.Classify the bond in NBr3 as ionic or covalent. If the bond is covalent, indicate whether it is polar or nonpolar. The bonds S-S, O-H and Ca-Cl are, respectively, a.nonpolar covalent, polar covalent, ionic b.polar covalent, nonpolar covalent, ionic c.ionic, polar covalent, nonpolar covalent d.nonpolar covalentAnd there's a very small difference in electronegativity between the carbon and the hydrogen. And that small difference is canceled out in three dimensions. So the methane molecule becomes nonpolar as a result of that. So this one's nonpolar, and, of course, this one's nonpolar. And so there's no dipole-dipole interaction. There's no hydrogen ... The steric number of Xenon central atom in the XeO3 molecule is 4, thus, it forms Sp 3 hybridization. XeO3 is a polar molecule. The molecular geometry of XeO3 is trigonal pyramidal and its electron geometry is tetrahedral. Each oxygen atom in the XeO3 lewis structure has 4 electrons that do not involve in bonding.Answer = C2F2 ( Ethyne ) is Nonpolar. What is polar and non-polar? Polar. "In chemistry, polarity is a separation of electric charge leading to a molecule or its chemical groups having an electric dipole or multipole moment. Polar molecules must contain polar bonds due to a difference in electronegativity between the bonded atoms.So the difference in electronegativity is somewhere between 1.5 and 2.1, between a polar covalent bond and an ionic bond. So most textbooks we'll see approximately somewhere around 1.7. So if you're higher than 1.7, it's generally considered to be mostly an ionic bond. Lower than 1.7, in the polar covalent range.The compound with the chemical formula CF4, carbon tetrafluoride, is nonpolar. Unlike other molecules that are nonpolar because they feature only nonpolar bonds, CF4 has this prope...Expert Answer. CO3^2- ion is NON - POLAR because CO3^2- ion is trigonal planar geometry due to sp2 Hybridizat …. View the full answer.Notice that a tetrahedral molecule such as CCl4 CCl 4 is nonpolar Figure ( 4.12.1 4.12. 1. Another non polar molecule shown below is boron trifluoride, BF 3. BF 3 is a trigonal planar molecule and all three peripheral atoms are the same. Figure 4.12.1 4.12. 1 Some examples of nonpolar molecules based on molecular geometry (BF 3 and CCl 4 ).Answer = Na2CO3 ( sodium carbonate ) is Nonpolar. What is polar and non-polar? Polar. "In chemistry, polarity is a separation of electric charge leading to a molecule or its chemical groups having an electric dipole or multipole moment. Polar molecules must contain polar bonds due to a difference in electronegativity between the bonded atoms.Both CO2 and H2O contain polar covalent bonds but CO2 is non-polar while H2O is polar because: H atom is smaller than C atom; CO2 is a linear molecule while ...Yes, water (H2O) is polar. This is because of the bent shape of the water molecule due to which there is an unequal charge distribution over the atoms of hydrogen and oxygen involved in the molecule of water. Therefore, the water molecule possesses a net dipole moment. Being a tasteless and odorless liquid compound at room …Oct 5, 2020 · ~The molecular geometry in both CH2F2 and CF4 is tetrahedral (or the same). The C-F bond is polar. In CF4, the molecular geometry arranges the C-F dipoles so that they cancel out and the molecule is nonpolar. ~The C-H bond is less polar than the C-F bond. The two C-H dipoles do not cancel the two C-F dipoles in CH2F2 Apr 28, 2022 · The base of HCO3 would be the CO3 2- polyatomic ion. This has a trigonal pyramidal shape according to VSEPR theory. Each oxygen will be spaced evenly around the carbon atom and thus the individual ... In OF2, the Oxygen atom is the least electronegative one and hence it is placed in the centre. Fluorine is highly electronegative and has an electronegative value of 3.98, whereas Oxygen has an electronegative value of 3.44. The difference between the electronegativities of both these atoms is higher than 0.5, which makes the O-F bonds polar.Now in the next step we have to check whether these As-Cl bonds are polar or nonpolar. And we also have to check the molecular geometry of AsCl3. Step #2: Check whether individual bonds are polar or nonpolar. The chemical bonds can be either nonpolar, polar or ionic depending on the difference of the electronegativity values …Speciation events are when members of the same species separate until they are no longer able to reproduce with each other. Learn more about speciation events. Advertisement Have y...A molecule (or polyatomic ion) is polar when one side of the molecule is more positive (or more negative) than the other. This occurs when the polarities of the …Few areas in tech are as polarized as the blockchain gaming space -- but the ecosystem around blockchain games is already getting built and funded. Few areas in tech today are as p...Aug 10, 2022 · Notice that a tetrahedral molecule such as CCl4 CCl 4 is nonpolar Figure ( 4.12.1 4.12. 1. Another non polar molecule shown below is boron trifluoride, BF 3. BF 3 is a trigonal planar molecule and all three peripheral atoms are the same. Figure 4.12.1 4.12. 1 Some examples of nonpolar molecules based on molecular geometry (BF 3 and CCl 4 ). Crypto in the U.S. is more polarized and politicized than ever.Ironically, that’s a sign that the issues around this technology have become less o... Crypto in the U.S. is more pol...Polarity therapy is an alternative medicine approach. Here's all you need to know about it, including what research says about its effectiveness. If you’re looking for an intervent...Learn to determine if CH3COOH (Acetic acid) is polar or non-polar based on the Lewis Structure and the molecular geometry (shape).We start with the Lewis Str...Aug 20, 2023 · Is CO3 2- Polar or Non-Polar? Understanding the Molecule’s Polarity. Carbonate ion, with the chemical formula CO3 2-, is a common molecule that plays a crucial role in many chemical and biological processes. One of the most common questions that arise about this molecule is whether it’s polar or non-polar. Hello Everyone! Carbonate ion is a polyatomic ion with the formula CO3-2. It is a carbon oxoanion. In this video, we have determined if the carbonate ion is polar or nonpolar.In this article, we will discuss Carbon dioxide (CO2) lewis structure, molecular geometry or shape, electron geometry, bond angle, hybridization, polar or nonpolar, etc. At room temperature, carbon dioxide normally acts as gas but at high pressure, it …SF2 is a polar molecule but its bonding angle is very interesting. The bond angle of SF2 is 98 degree and that of H2O is 104 degrees. The reason for this fact is the presence of highly negative halogen fluorine. 2 fluorine atoms are present either side of the molecule. The presence of lone pair electrons causes negative-negative charge repulsion.A molecule (or polyatomic ion) is polar when one side of the molecule is more positive (or more negative) than the other. This occurs when the polarities of the …Show transcribed image text Is the following compound predicted to be polar or nonpolar? O nonpolar O polar . Als CSe2 polar or nonpolar?( B B. Is CH4 polar or nonpolar? C. Is BrCl3 polar or nonpolar? Submit Answer Retry Entire Group 9 mo . Weekly leaderboard. Home. Homework Help 3,900,000. Chemistry 830,000. Start filling …Polarization - Photochromatic sunglasses are sunglasses that darken when exposed to light. Find out how photochromatic sunglasses work in this section. Advertisement Light waves fr...Get the detailed answer: Is CO3-2 polar or nonpolar? ... Show transcribed image text Is the following compound predicted to be polar or nonpolar? O nonpolar O polar . Als CSe2 polar or nonpolar?( B B. Is CH4 polar or nonpolar? C. Is BrCl3 polar or nonpolar? Submit Answer Retry Entire Group 9 mo .In OF2, the Oxygen atom is the least electronegative one and hence it is placed in the centre. Fluorine is highly electronegative and has an electronegative value of 3.98, whereas Oxygen has an electronegative value of 3.44. The difference between the electronegativities of both these atoms is higher than 0.5, which makes the O-F bonds polar.They're going to stay in the middle. They're going to be shared between those two atoms. So this is a covalent bond, and there's no polarity situation created here since there's no …The electronegativity difference (ΔEN) = 3.16 – 2.58 = 0.58. This value lies between 0.4 to 2.0, which indicates that the bond between Sulfur (S) and Chlorine (Cl) is polar. Hence, each S-Cl bond is a polar covalent bond. You can see in the above image that because of large electronegativity difference of Sulfur and Oxygen atoms, the partial ...Answer = TeCl4 ( Tellurium tetrachloride ) is Polar. What is polar and non-polar? Polar. "In chemistry, polarity is a separation of electric charge leading to a molecule or its chemical groups having an electric dipole or multipole moment. Polar molecules must contain polar bonds due to a difference in electronegativity between the bonded atoms.Now in the next step we have to check whether these bonds are polar or nonpolar. And we also have to check the molecular geometry of COCl2. Step #2: Check whether individual bonds are polar or nonpolar. The chemical bonds can be either nonpolar, polar or ionic depending on the difference of the electronegativity values …Determine the central atom In the carbonate ion, carbon (C) is the central atom as it is less electronegative than oxygen (O) and can form multiple bonds. 3. Connect the atoms with …Since that is the case above (0.86), we can safely say that the S-O bonds are polar. Molecular Shape and Symmetry. Observing the Lewis structure and molecular shape will further help us determine whether SO 2 is polar or non-polar. From the Lewis structure, it is evident that the molecule is vertically symmetrical. However, the presence of two ...Oct 18, 2023 · is sih2cl2 polar or nonpolar? is cs2 polar? Final Thought. POCl3, or phosphoryl chloride, adopts a pyramidal geometrical structure. This means it consists of one central phosphorus atom (P) bonded to one oxygen atom (O) and three chlorine atoms (Cl), with bond angles of approximately 107 degrees. Compared with the monster seas of the Pacific, Arctic waters are a picture of calm—whipping up, at their most violent, into lake-like chop. Or, at least, they were. New research sh...Let’s dive into it! I2 is a NONPOLAR molecule because any two bonding atoms whose electronegativity difference value is less than 0.4 forms a nonpolar bond. Here in I2 molecule, both the atoms are Iodine atoms. Because of this, the electronegativity difference of both the Iodine atoms (I = 2.66) is 0 (i.e 2.66 – 2.66 = 0).Want to know the reason? Let’s dive into it! SO3 2- is a POLAR ion because the Oxygen (O) atom is more electronegative and it also has lone pair, which results in …Winter Storm Grayson is bringing snow and ice, followed by a frigid polar vortex. Here are 10 great clothing deals to keep you warm. By clicking "TRY IT", I agree to receive newsle...1 Bond polarity and molecular polarity are different (though related) concepts. In short the molecular dipole moment is the vector sum of the individual bonds dipole moments, so you have to know the geometry …Sulfur dioxide (SO2) is a polar molecule. 2. What type of bond is SO2: polar or nonpolar? The bond in SO2 is a polar covalent bond.. 3. Why is SO2 polar and SO3 nonpolar? SO2 is polar because it has a bent molecular geometry and a significant dipole moment, while SO3 is nonpolar due to its trigonal planar molecular geometry and a …Oct 11, 2022 · The Lewis structure of carbonate [CO3]2- ion is made up of a carbon (C) atom and three oxygen (O) atoms. The carbon (C) is present at the center of the molecular ion while oxygen (O) occupies the terminals, one on each side. There are a total of 3 electron density regions around the central C atom in the Lewis structure of [CO3]2-. The compound with the chemical formula CF4, carbon tetrafluoride, is nonpolar. Unlike other molecules that are nonpolar because they feature only nonpolar bonds, CF4 has this prope...Oct 14, 2023 · Carbonate (CO 32-) is a non-polar molecular ion. It consists of polar bonds (one C=O and two C-O bonds) due to an electronegativity difference of 0.89 units between the bonded C-atom (E.N =2.55) and O-atom (E.N =3.44). Carbonate CO 32- ion has a symmetrical trigonal planar shape with a 120 ° mutual bond angle. SF4. polar (see saw) ICl5. polar (square pyramidal) Polar molecular geometry. bent, trigonal pyramidal, see saw, trigonal bipyramidal. Non-polar molecular geometry. linear, tetrahedral, trigonal planar. Study with Quizlet and memorize flashcards containing terms like CH4, NH3, H2O and more. Carbon forms double bonds with some oxygen atoms in CO3 2- to achieve a stable electronic configuration. By sharing two pairs of electrons in a double bond, carbon satisfies the octet rule, having a total of eight valence electrons around it. 3. Is CO3 2- polar or nonpolar? The carbonate ion, CO3 2-, is a nonpolar ion. Answer = CH3CH2NH2 is Polar. What is polar and non-polar? Polar. "In chemistry, polarity is a separation of electric charge leading to a molecule or its chemical groups having an electric dipole or multipole moment. Polar molecules must contain polar bonds due to a difference in electronegativity between the bonded atoms.To determine if CH 2 O (formaldehyde ) is polar or nonpolar, we need to first determine its geometry.This presumes knowing the rules for drawing a correct Lewis structure and you can find more details about Lewis structures here.. The carbon is the central atom: There is a total of 4 + 2×1 + 6 = 12 electrons, and 6 are already used for making the bond. The …This value is less than 0.4, which indicates that the bond between Carbon (C) and Hydrogen (H) is nonpolar. Hence, each C-H bond is a nonpolar covalent bond. For C-F bond; The electronegativity difference (ΔEN) = 3.98 – 2.55 = 1.43. This value lies between 0.4 to 1.7, which indicates that the bond between Carbon (C) and Fluorine (F) is …This problem has been solved! You'll get a detailed solution from a subject matter expert that helps you learn core concepts. Question: Can you show (CO3) -2 is nonpolar but (SO3) -2 is polar. Please explain nicely. I am confused because one of them has the shape trigonal planar and the other one's shape is trigonal pyramidal. The electronegativity of Nitrogen is 3.04 and that of hydrogen is 2.2. The difference between their electronegativity generates the polarity across the N-H bond. As a result, the N-H bond is polar in the NH4+ molecule. The dipole value of NH4+ ions is also non zero. But due to the symmetrical arrangement of N-H bonds, the dipoles get …I'll tell you the polar or nonpolar list below. If you want to quickly find the word you want to search, use Ctrl + F, then type the word you want to search. ... CO3 2- (Carbonate) Nonpolar: CS: Nonpolar: CS2 (CARBON DISULFIDE) Nonpolar: CSe2: Nonpolar: cyclohexane: Nonpolar: Cysteine: Nonpolar: decane: Nonpolar: diethyl ether ( …Oxidation-Reduction. None. This page titled Carbonate Ion (CO₃²⁻) is shared under a CC BY-NC-SA 4.0 license and was authored, remixed, and/or curated by James P. Birk. Carbonate ion, a moderately strong base, undergoes considerable hydrolysis in aqueous solution. In strongly acidic solution, CO2 gas is evolved.It is a polar molecule because it is asymmetrical and has a negative pole and a positive pole. Polar. It is pyramidal, and the electrons will congregate around the chlorines, creating a dipole ...CO3 2- (Carbonate) is Nonpolar. I'll tell you the polar or nonpolar list below. If you want to quickly find the word you want to search, use Ctrl + F, then type the word you want to search. List molecules polar and non polar. Molecules polar. 1-butanol.Crypto in the U.S. is more polarized and politicized than ever.Ironically, that’s a sign that the issues around this technology have become less o... Crypto in the U.S. is more pol...Now in the next step we have to check whether these Cl-F bonds are polar or nonpolar. And we also have to check the molecular geometry of ClF5. Step #2: Check whether individual bonds are polar or nonpolar. The chemical bonds can be either nonpolar, polar or ionic depending on the difference of the electronegativity values …May 25, 2023 · Now in the next step we have to check whether these bonds are polar or nonpolar. And we also have to check the molecular geometry of COF2. Step #2: Check whether individual bonds are polar or nonpolar. The chemical bonds can be either nonpolar, polar or ionic depending on the difference of the electronegativity values (ΔEN) between the two atoms. Answer = C2Cl2 is Polar. What is polar and non-polar? Polar. "In chemistry, polarity is a separation of electric charge leading to a molecule or its chemical groups having an electric dipole or multipole moment. Polar molecules must contain polar bonds due to a difference in electronegativity between the bonded atoms.HowStuffWorks finds out whether it's ever a good idea to have a political discussion at work and if so, how to do it. Advertisement There you are, innocently microwaving last night...Answer = C2Cl2 is Polar. What is polar and non-polar? Polar. "In chemistry, polarity is a separation of electric charge leading to a molecule or its chemical groups having an electric dipole or multipole moment. Polar molecules must contain polar bonds due to a difference in electronegativity between the bonded atoms.The electronegativity difference (ΔEN) = 2.58 – 2.55 = 0.03. This value is less than 0.4, which indicates that the bond between Carbon (C) and Sulfur (S) is nonpolar. Hence, each C-S bond is a nonpolar covalent bond. For Carbon-Nitrogen bond; The electronegativity difference (ΔEN) = 3.04 – 2.55 = 0.49.Carbonyl Fluoride (COF2) is a polar molecule because of the electronegativity difference between oxygen and fluorine. Fluorine is the most electronegative element in the periodic table. Hence, it gains a slight negative charge as it attracts electrons more than that of oxygen, creating a slight positive charge on the carbon atom.Nitrogen Dioxide (NO2) Polar or Nonpolar (Basis of Characteristics) NO2 is a polar molecule and the Oxygen atom closest to negative side as the electronegativity of Oxygen (3.44) is comparatively greater than Nitrogen (3.04) so that Nitrogen has a partial positive charge and Oxygen has a partial negative charge established within the molecule.Now in the next step we have to check whether these I-F bonds are polar or nonpolar. And we also have to check the molecular geometry of IF3. Step #2: Check whether individual bonds are polar or nonpolar. The chemical bonds can be either nonpolar, polar or ionic depending on the difference of the electronegativity values …Compared with the monster seas of the Pacific, Arctic waters are a picture of calm—whipping up, at their most violent, into lake-like chop. Or, at least, they were. New research sh...
The main difference between polar molecules and nonpolar molecules lies in the arrangement of atoms in the molecule. Additionally, polar molecules have an electrical field charge, .... Peter piper pizza near me
CH3COOH is a polar molecule in nature because of the unequal distribution of charge on the atom that leads to some net dipole moment. In acetic acid lewis structure, there are 3 C-H bonds, 1 C=O. …1 day ago · CO2 (carbon dioxide) is a nonpolar molecule because of its linear symmetric shape. Although the carbon and oxygen differ in their electronegativity due to which C=O bond is polar, the polarity of both opposite C=O bonds get canceled by each other due to symmetrical shape and result in a nonpolar molecule with zero dipole moment. Yes, water (H2O) is polar. This is because of the bent shape of the water molecule due to which there is an unequal charge distribution over the atoms of hydrogen and oxygen involved in the molecule of water. Therefore, the water molecule possesses a net dipole moment. Being a tasteless and odorless liquid compound at room …They're not the same thing. In the midst of “cancel culture” and living in an extremely politically polarized society, it’s not uncommon to receive feedback from other people. In f...Oct 5, 2020 · ~The molecular geometry in both CH2F2 and CF4 is tetrahedral (or the same). The C-F bond is polar. In CF4, the molecular geometry arranges the C-F dipoles so that they cancel out and the molecule is nonpolar. ~The C-H bond is less polar than the C-F bond. The two C-H dipoles do not cancel the two C-F dipoles in CH2F2 Aug 20, 2023 · Is CO3 2- Polar or Non-Polar? Understanding the Molecule’s Polarity. Carbonate ion, with the chemical formula CO3 2-, is a common molecule that plays a crucial role in many chemical and biological processes. One of the most common questions that arise about this molecule is whether it’s polar or non-polar. Hello Everyone! Carbonate ion is a polyatomic ion with the formula CO3-2. It is a carbon oxoanion. In this video, we have determined if the carbonate ion is polar or nonpolar.The molecular mass of the SCl2 compound is 102.97 g·mol−1, calculated as below. Mol mass of SCl2 = 1 * 32 (Mol mass of S) + 2 * 35.4 (Mol mass of Cl) = 102.97 g·mol−1. If we talk about the chemical composition of the Sulfur dichloride, the molecule consists of 2 atoms of chlorine and 1 sulfur atom. Sulfur is the central atom surrounded by ...Show transcribed image text Is the following compound predicted to be polar or nonpolar? O nonpolar O polar . Als CSe2 polar or nonpolar?( B B. Is CH4 polar or nonpolar? C. Is BrCl3 polar or nonpolar? Submit Answer Retry Entire Group 9 mo . Weekly leaderboard. Home. Homework Help 3,900,000. Chemistry 830,000. Start filling …There's a jazz festival in the middle of the arctic circle, in a Norwegian town called Longyearbyen, which is known for its views of the Northern Lights. File this one under one of....
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